1)

The arrangement of X- ions around A+ ion in solid AX is  given in the figure (not drawn to scale ) . If tythe radius of X- is 250 pm, the radius of A- is 

1042021358_c2.JPG


A) 104 pm

B) 125 pm

C) 183 pm

D) 57 pm

Answer:

Option A

Explanation:

Plan  Given arrangement represents octahedral  void and fix this 

                   $\frac{r_{+}(cation)}{r_{-}(anion)}=0.414$

$\frac{r(A^{+})}{r(X^{-})}=0.414$

 $r(A^{+}){}=0.414\times r(X^{-})$

   $=0.414\times250pm=103.5 pm$