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1)

Consider the reaction : N2 + 3H2 → 2NHcarried out at constant temperature and pressure. If ΔH and ΔU are the enthalpy and internal energy changes for the reaction, which of the following expressions is true ?


A) H>U

B) H<U

C) H=U

D) H=0

Answer:

Option B

Explanation:

ΔH = ΔU + ΔnRT for

N2 + 3H2 → 2NH3

Δng = 2 - 4 = -2

.'. ΔH = ΔU - 2RT or  ΔU = ΔH+2RT  .'. ΔU > ΔH