1)

Consider the following changes

M(s)M(g)  ......(i)

M(g)M2+(g)+2e   ...(2)

M(g)M+(g)+e    ....(3)

M+(g)M2+(g)+e  .....(4)

M(g)M2+(g)+2e   .......(5)

The second ionisation energy of M  could be determined from the energy values associated  with


A) 1+2+4

B) 1+5-3

C) 2+3-4

D) 5-3

Answer:

Option D

Explanation:

The amount  of energy required to take out an electron from the monopositive cation is called second ionisation energy

M(g)M2+(g)+2e  ....(v)

 M(g)M+(g)+e   ....(iii)

 On substracting eq(iii) from eq.(v)  we get,

 MM2++e