1)

Among the following , the correct statement(s) is (are)


A) $Al(CH_{3})_{3}$ has the three centre two -electron bonds in its dimeric structure

B) The lewis acidity of $BCl_{3}$ is greater than that of $AlCl_{3}$

C) $AlCl_{3}$ has the three centre two electron bonds in its dimeric structure

D) $BH_{3}$ has the three centre two electron bonds in its dimeric structure

Answer:

Option A,B,D

Explanation:

(a)

182202048_compound 5.JPG

(b)

1822020533_compound 6.JPG

(c) BCl3  is stronger Lewis acid than AlCl3  due to greatest extent of  $P_{\pi}-P_{\pi}$ back bonding in AlCl3

(d)

  272202034_11-pics.JPG