1)

18 g of glucose (C6H12O6) is added to 178.2 g water. The vapor pressure of water (in torr) for this aqueous solution


A) 76.0

B) 752.4

C) 759

D) 7.6

Answer:

Option B

Explanation:

Key concept :

Vapour pressure of water (po) = 760 torr

Number of moles of glucose = Mass(g)Molecularmass(g/mol)

=18g180gmol1=0.1mol

Molar mass of water= 18 g/mol

Mass of water (given) = 178.2g

Number of moles of water= MassofwaterMolarmassofwater

=178.218g/mol=9.9mol

Total number of moles = (0.1+ 9.9)moles = 10 moles

Now, mole fraction of glucose in solution = Change in pressure with respect to initial pressure

ie Δppo=0.110

or Δp=0.01po

=0.01×760=7.6torr

Vapour pressure of solution = (760-7.6) torr

                                         = 752.4 torr