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1)

The correct statement (s) about the following reaction sequence is (are)  

 Cumene(C6H12) (ii)H2O(i)O2 P   CHCl3/NaOHQ(major) +R (minor),

QPhCH2BrNaOHS


A) R is stream volatile

B) Q gives dark violet colouration with 1% aqueous FeCl3 solution

C) S gives yellow precipitate with 2,4-dinitrophenylhydrazine

D) S gives dark violet colouration with 1% aqueous FeCl3 solution.

Answer:

Option B,C

Explanation:

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1822021228_c20.JPG

182202149_c21.JPG

(a) R is not steam volatile , but Q is steam volatile thus, incorrect.

(b) Q has enolic group thus, gives violet colour with 1% aqueous  FeCl3 solution thus, correct.

 (c) S has carbonyl group hence, gives yellow precipitate with 2, 4-DNP  thus, correct.

(d) S does not give colour with FeCl3 thus, incorrect.