1)

Reagent(s)  which  can be  used to bring about the following transformation is (are)

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A) LiAlH4in(C2H5)2O

B) BH3 in THF

C) NaBH4 in C2H5OH

D) Raney Ni/H2 in THF

Answer:

Option C

Explanation:

Only -CHO group is to be reduced to -CH2OH

   It can be done using NaBH4  in  C2H5OH

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(a)LiAlH4/(C2H5)2O reduces I,II and III  into - CH2OH , and IV  into diol.

(b) BH3 / THF show same properties as (a)

(c) NaBH4C2H5OH reduces  III into -CH2OH

(d) Raney nickel, same as (a) and (b) thus (c) is correct reagent