Answer:
Option C,D
Explanation:
Only radicals of I and II group of qualitative analysis get precipitated with H2S in the presence of dilute HCL
(c) $Cu^{2+}+H_{2}S$ $\underrightarrow{H^{+}} $ $CuS \downarrow$
Black
$Pb^{2+}+H_{2} S $ $\underrightarrow{H^{+}} $ $PbS\downarrow $
Black
(d) $Hg^{2+}+H_{2} S $ $\underrightarrow{H^{+}} $ $HgS\downarrow $
Black
$Bi^{3+}+H_{2} S $ $\underrightarrow{H^{+}} $ $Bi_{2}S_{3}$ $\downarrow $
Brown ppt
Ba2+ , Zn2+ and Fe3+ are not precipitated as sulphide.