1)

Match the orbital overlap figures shown in List I with the description given in List-II  and select the correct answer using the code given below the lists.

2732021516_m11.PNG


A) P:2,Q:1,R:3,S:4

B) P:4,Q:3,R:1,S:2

C) P:2,Q:3,R:1,S:4

D) P:4,Q:1,R:3,S:2

Answer:

Option C

Explanation:

Plan  This problem includes basic concept of bonding. It can be solved by using the concept of molecular orbital theory

Any orbital has two-phase +ve and -ve. In the following  diagram +ve phase  is shown by darkening the lobes and -ve by without  darkening the lobes

 2832021823_p11.JPG

 

 When two same phase overlap  with each other it forms bonding molecular orbital otherwise antibonding

2832021769_p12.JPG

 Axial overlapping leads to the formation of σ  -bond and sideways overlapping leads to the formation of  $\pi$- bond

2832021839_p13.JPG

 On the basis of above two concepts correct matching can be done as shown below

 

2832021785_p14.JPG

P → 2, Q → 3, R→  1, S→ 4

Hence ,(c)  is the correct option