1) A piston filled with 0.04 mole of an ideal gas expands reversibly from 50.0 ml to 375 ml at a constant temperature of 37.0° , As it does so, it absorbs 208 J of heat. The values of q and W for the process will be (R=8.314 J/mol K, ln 7.5 =2.01) A) q=+ 208J,W=-208 J B) q=- 208J,W=- 208 J C) q=- 208J,W=+208 J D) q=+ 208J,W= + 208 J Answer: Option AExplanation:The process is isothermal expansion, hence Q=-W $\triangle E=0$ $W=2.303 nRT log \frac{V_{2}}{V_{1}}$ $=2.303\times0.04\times 8.314 \times310 \times log \frac{335}{50}$ =-208 J Q=+208J w= -208 J (expansion work)