1)

 The unbalanced chemical reactions give in list I show missing reagent or condition (?)  which are provided in list II. Match List I with List II  and select the correct answer using the code given below the lists 

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A) P:4, Q:2, R:3, S:1

B) P:3, Q:2, R:1, S: 4

C) P:1, Q:4, R: 2, S:3

D) P:3, Q:4, R:2, S:1

Answer:

Option D

Explanation:

(P)   2PbO2+2H2SO4    warm(3)         2PbSO4+O2+2H2O

(Q)    Na2S2O3+H2O     Cl2(4) NaHSO4+HCl

 (R)      N2H4   I2(2)  N2+HI

(S)     XeF2        NO(1)  Xe+NOF

 Thus , P - (3) , Q - (4), R- (2), S -(1)