Answer:
Option D
Explanation:
(P) $2PbO_{2}+2H_{2}SO_{4}$ $\underrightarrow{warm(3)}$ $ 2PbSO_{4}+O_{2}+2H_{2}O$
(Q) $Na_{2}S_{2}O_{3}+H_{2}O $ $\underrightarrow{Cl_{2}(4)}$ $NaHSO_{4}+HCl$
(R) $N_{2}H_{4} $ $\underrightarrow{I_{2}(2)}$ $ N_{2}+HI$
(S) $XeF_{2}$ $\underrightarrow{NO(1)}$ Xe+NOF
Thus , P - (3) , Q - (4), R- (2), S -(1)