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1)

With reference to the scheme given which of the given statement (s) about T, U, V and W is (are) correct?

11112021267_k6.PNG


A) T is soluble in hot aqueous NaOH.

B) U is optically active

C) Molecular formula of W is C10H18O4

D) V gives effervescence on treatment with aqueous NaHCO3

Answer:

Option A,C,D

Explanation:

(a) T is an ester hydrolysis in hot aqueous alkali

11112021296_j1.PNG

(b) LiAlH4 reduces ester to alcohol as

11112021912_j2.PNG

'U" No chiral carbon optically inactive'
(c) U on treatment with an excess of acetic anhydride forms a diester as

11112021780_j3.PNG

(d) U on treatment with CrO3 l H+  undergo oxidation to diacid which gives
effervescence with NaHCO3

11112021716_j4.PNG